Binding Energy per Nucleon Curve
- In order to compare nuclear stability, it is useful to look at the binding energy per nucleon
- The binding energy per nucleon is defined as:
The binding energy of a nucleus divided by the number of nucleons in the nucleus
- A higher binding energy per nucleon indicates a higher stability
- In other words, more energy is required to separate the nucleons contained within a nucleus
By plotting a graph of binding energy per nucleon against nucleon number, the stability of elements can be inferred
Key Features of the Graph
- At low values of A:
- Nuclei have lower binding energies per nucleon than at large values of A, but they tend to be stable when N = Z
- This means light nuclei have weaker electrostatic forces and will undergo fusion
- The gradient is much steeper compared to the gradient at large values of A
- This means that fusion reactions release a greater binding energy than fission reactions
- At high values of A:
- Nuclei have generally higher binding energies per nucleon, but this gradually decreases with A
- This means the heaviest elements are the most unstable and will undergo fission
- The gradient is less steep compared to the gradient at low values of A
- This means that fission reactions release less binding energy than fission reactions
- Iron (A = 56) has the highest binding energy per nucleon, which makes it the most stable of all the elements
- Helium (4He), carbon (12C) and oxygen (16O) do not fit the trend
- Helium-4 is a particularly stable nucleus hence it has a high binding energy per nucleon
- Carbon-12 and oxygen-16 can be considered to be three and four helium nuclei, respectively, bound together
Comparing Fusion & Fission
Similarities
- In both fusion and fission, the total mass of the products is slightly less than the total mass of the reactants
- The mass defect is equivalent to the binding energy that is released
- As a result, both fusion and fission reactions release energy
Differences
- In fusion, two smaller nuclei combine into a larger nucleus
- In fission, an unstable nucleus splits into two smaller nuclei
- Fusion occurs between light nuclei (A < 56)
- Fission occurs in heavy nuclei (A > 56)
- In light nuclei, attractive nuclear forces dominate over repulsive electrostatic forces between protons, and this contributes to nuclear stability
- In heavy nuclei, repulsive electrostatic forces between protons begin to dominate over attractive nuclear forces, and this contributes to nuclear instability
- Fusion releases much more energy per kg than fission
- Fusion requires a greater initial input of energy than fission
Worked example
The equation below represents one possible decay of the induced fission of a nucleus of uranium-235.
The graph shows the binding energy per nucleon plotted against nucleon number A.
Calculate the energy released
Answer:
Part (a)
Step 1: Use the graph to identify each isotope’s binding energy per nucleon
- Binding energy per nucleon (U-235) = 7.5 MeV
- Binding energy per nucleon (Sr-91) = 8.2 MeV
- Binding energy per nucleon (Xe-142) = 8.7 MeV
Step 2: Determine the binding energy of each isotope
Binding energy = Binding Energy per Nucleon × Mass Number
- Binding energy of U-235 nucleus = (235 × 7.5) = 1763 MeV
- Binding energy of Sr-91 = (91 × 8.2) = 746 MeV
- Binding energy of Xe-142 = (142 × 8.7) = 1235 MeV
Step 3: Calculate the energy released
Energy released = Binding energy after (Sr + Xe) – Binding energy before (U)
Energy released = (1235 + 746) – 1763 = 218 MeV
Part (b)
Step 1: Calculate the energy released by 1 mol of uranium-235
- There are NA (Avogadro’s number) atoms in 1 mol of U-235, which is equal to a mass of 235 g
- Energy released by 235 g of U-235 = (6 × 1023) × 218 MeV
Step 2: Convert the energy released from MeV to J
- 1 MeV = 1.6 × 10–13 J
- Energy released = (6 × 1023) × 218 × (1.6 × 10–13) = 2.09 × 1013 J
Step 3: Work out the proportion of uranium-235 in the sample
- 1 kg of uranium which is 3% U-235 contains 0.03 kg or 30 g of U-235
Step 4: Calculate the energy released by the sample
Energy released from 1 kg of Uranium =
Exam Tip
Checklist on what to include (and what not to include) in an exam question asking you to draw a graph of binding energy per nucleon against nucleon number:
- Do not begin your curve at A = 0, this is not a nucleus!
- Make sure to correctly label both axes AND units for binding energy per nucleon
- You will be expected to include numbers on the axes, mainly at the peak to show the position of iron (56Fe)