Amount of Substance
- The mole is one of the seven SI base units
- It is used to measure the amount of substance, not a mass
- One mole is defined as follows:
The amount of substance that contains as many elementary entities as the number of atoms in 12 g of carbon-12
- This amount of substance is exactly 6.02214076 × 1023 elementary entities (i.e. particles, atoms, molecules)
- At IB level, this number can be rounded to 6.02 × 1023
- One mole of gas contains a number of particles (atoms or molecules) equal to the Avogadro Constant
- For example, 1 mole of sodium (Na) contains 6.02 × 1023 atoms of sodium
- The number of atoms can be determined if the number of moles is known by multiplying by NA.
- For example: 2.0 mol of argon contains: 2.0 × NA = 2.0 × 6.02 × 1023 = 1.20 × 1024 atoms
- The number of moles, n of a substance can be calculated using the equation
- Where:
- N = number of particles (molecules or atoms, depending on the substance)
- n = number of moles of gas (mol)
- NA = 6.02 × 1023 mol–1 (Avogadro constant)
Molar Mass
- One mole of any element is equal to the relative atomic mass of that element in grams
- E.g. Helium has a relative atomic mass of 4 - this means 1 mole of helium has a mass of 4 g
- If the substance is a compound, add up the relative atomic masses, for example, water (H2O) is made up of
- 2 hydrogen atoms (each with atomic mass of 1) and 1 oxygen atom (atomic mass of 16)
- So, 1 mole of water would have a mass of (2 × 1) + 16 = 18 g
- The molar mass, m of a substance is defined as the mass m of the substance divided by the amount (in moles) of that substance
- The molar mass is calculated as follows:
- Where:
- mr = molar mass in g mol–1
- m = mass in grams (g)
- n = number of moles (mol)
Worked example
120 moles of nitrogen gas are in a container.
Calculate the number of nitrogen gas molecules in the container.
Answer:
Step 1: List the known quantities
- Number of moles, n = 120
Step 2: Rearrange the number of moles equation for the number of molecules, N
Step 3: Substitute in the values
molecules
Worked example
A container is filled with 2.6 × 1020 molecules of argon gas which has a mass number of 40.
Calculate the total mass of argon in the container.
Answer:
Step 1: List the known quantities
- Number of argon gas molecules, N = 2.6 × 1020
- Molar mass of argon, mr = 40 g mol–1 (same as the atomic mass)
Step 2: Calculate the number of moles of argon in the container
Step 3: Calculate the total mass of the argon in the container
Exam Tip
The value of the Avogadro constant is given on your data sheet, so you don't need to learn this value. However, it does help make calculations quicker if you do!
Take care with the units for molar mass, this is g mol–1, so multiplying by the number of moles gives a mass in grams and not kilograms.